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As regards the "Quad SQ Stereo" CD" included in the 2012 box set of Machine Head , it is a fold-down of the EMI quad mix from 1972.. The box also includes on a DVD disc the EMI quad mix repurposed to 4.1
As regards what constitutes the 'original' quad mix, the EMI quad mix came first in 1972, then the Warner quad mix in 1974, as steelydave notes.
I'm not so sure the UK quad (Sq and Q8) were really released in 1972. 1972 is the Copyright year for MH, stereo, but if the Q8 MH would had been released in 1972 it would have a colour slick on the cart, not the b/w that were common by late 1973/early 1974 (for example, DSOTM).
One will need to look at a EMI catalogue to be sure of that.
EDIT: images.
1) early (1972) EMI UK Q8 slick. Never seen MH with that kind of configuration.
2) later (1974) EMI UK Q8 cover and slick. MH does have these. Please note this is a second Q8 edition of Space Experience (it does exist also as 1) and it list 1972 as release year.